Valorization of pistachio shells as green composite material: an approach that contributes to sustainable development

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Authors

DOI:

https://doi.org/10.56845/rebs.v8i1.672

Keywords:

biocomposite material, pistachio shells, agro-industrial waste, sustainable material

Abstract

The increase in the production of conventional plastics has generated an environmental crisis that is difficult to reverse. In response to this problem, this study proposes the development of a green composite material (GCM) from pistachio shells and a matrix based on potato starch, calcium chloride (CaCl2) and polyvinyl alcohol (PVA). A series of steps were followed to prepare the GCM, including cleaning, drying, milling, sieving, mixing, compression molding and drying. Once the GCM was obtained, a perceptual analysis was performed and its microstructure and hardness were characterized by optical microscopy and Vickers tests, respectively. The granulometric analysis revealed that the milled sample had a high proportion of coarse particles with sizes ranging from 0.71 to 1.70 mm, which accounted for 74.98%. These particles exhibited a slightly elongated complex morphology (circularity = 0.73 ± 0.04 and aspect ratio = 1.27 ± 0.16). The GCM exhibited a compact structure with a low degree of porosity and a visual finish similar to that of wood chipboard. The perceptual analysis carried out with experts and non-experts, showed a good acceptance of the material, highlighting its innovation, stiffness. and sustainability as the most outstanding attributes. In the microstructural analysis, a heterogeneous distribution of the particles was observed, as well as the presence of irregular pores. Finally, Vickers hardness tests showed that the GCM exhibited a hardness value of 33.63 ± 16.49 HV, which is comparable to that of other biocomposite materials. In conclusion, it was possible to produce a GCM from pistachio shell waste with adequate physical characteristics, which represents an attractive and viable sustainable alternative to replace conventional plastics and   offers potential multiple applications in various industrial sectors.

References

Arzumanova, N. B. (2021). Polymer biocomposites based on agro waste: Part III. Shells of various nuts as natural filler for polymer composites. New Materials, Compounds and Applications, 5(1), 19–44.

Balasundar, P., Narayanasamy, P., Senthil, S., Al-Dhabi, N. A., Prithivirajan, R., Kumar, R. S., Ramkumar, T., & Bhat, K. S. (2019). Physico-chemical study of pistachio (Pistacia vera) nutshell particles as a bio-filler for eco-friendly composites. Materials Research Express, 6(10), 105339. https://doi.org/10.1088/2053-1591/ab3b9b

Carus, M., Eder, A., & Beckmann, J. (2014). GreenPremium prices along the value chain of biobased products. Industrial Biotechnology, 10(2), 83–88. https://doi.org/10.1089/ind.2014.1512

Huss, J. C., Antreich, S. J., Bachmayr, J., Xiao, N., Eder, M., Konnerth, J., & Gierlinger, N. (2020). Topological interlocking and geometric stiffening as complementary strategies for strong plant shells. Advanced Materials, 32(48), 2004519. https://doi.org/10.1002/adma.202004519

Kashaninejad, M., & Tabil, L. G. (2011). Pistachio (Pistacia vera L.). En E. M. Yahia (Ed.), Postharvest biology and technology of tropical and subtropical fruits (pp. 218–247e). Woodhead Publishing. https://doi.org/10.1533/9780857092618.218

Lala, S. D., Deoghare, A. B., & Chatterjee, S. (2018). Mechanical and morphological characterization of walnut shell reinforced epoxy composite. IOP Conference Series: Materials Science and Engineering, 377(1), 012011. https://doi.org/10.1088/1757-899X/377/1/012011

Manu, T., Nazmi, A. R., Shahri, B., Emerson, N., & Huber, T. (2022). Biocomposites: A review of materials and perception. Materials Today Communications, 31, 103308. https://doi.org/10.1016/j.mtcomm.2022.103308

Mariano, M., Zornio, C. F., Fakhouri, F. M., & Martelli, S. M. (2017). Influence of natural fillers size and shape into mechanical and barrier properties of biocomposites. En V. K. Thakur, M. K. Thakur, & M. R. Kessler (Eds.), Handbook of composites from renewable materials (1ª ed., pp. 459–487). Wiley. https://doi.org/10.1002/9781119441632.ch56

McNeill, D. C., Pal, A. K., Nath, D., Rodriguez-Uribe, A., Mohanty, A. K., Pilla, S., Gregori, S., Dick, P., & Misra, M. (2024). Upcycling of ligno-cellulosic nutshells waste biomass in biodegradable plastic-based biocomposites uses—A comprehensive review. Composites Part C: Open Access, 14, 100478. https://doi.org/10.1016/j.jcomc.2024.100478

Nicolás-Bermúdez, J., Arzate-Vázquez, I., Chanona-Pérez, J. J., Méndez-Méndez, J. V., Rodríguez-Castro, G. A., & Martínez-Gutiérrez, H. (2018). Morphological and micromechanical characterization of calcium oxalate (CaOx) crystals embedded in the pecan nutshell (Carya illinoinensis). Plant Physiology and Biochemistry, 132, 566–570. https://doi.org/10.1016/j.plaphy.2018.10.008

Nunes, F. M., Moraes, J. A. R., Machado, Ê. L., Lutterbeck, C. A., Rizzetti, T. M., & Santana, R. M. C. (2024). Rice-based biocomposites: The influence of the rice husk granulometry on physical and biodegradation properties of rice bran matrix biocomposites. Journal of Material Cycles and Waste Management, 26(5), 2935–2946. https://doi.org/10.1007/s10163-024-02009-2

Queirós, C. S. G. P., Cardoso, S., Lourenço, A., Ferreira, J., Miranda, I., Lourenço, M. J. V., & Pereira, H. (2020). Characterization of walnut, almond, and pine nut shells regarding chemical composition and extract composition. Biomass Conversion and Biorefinery, 10(1), 175–188. https://doi.org/10.1007/s13399-019-00424-2

Rafiee, K., Schritt, H., Pleissner, D., Kaur, G., & Brar, S. K. (2021). Biodegradable green composites: It’s never too late to mend. Current Opinion in Green and Sustainable Chemistry, 30, 100482. https://doi.org/10.1016/j.cogsc.2021.100482

Sauerwein, M., Karana, E., & Rognoli, V. (2017). Revived beauty: Research into aesthetic appreciation of materials to valorise materials from waste. Sustainability, 9(4), 529. https://doi.org/10.3390/su9040529

Taib, N.-A. A. B., Rahman, M. R., Huda, D., Kuok, K. K., Hamdan, S., Bakri, M. K. B., Julaihi, M. R. M. B., & Khan, A. (2023). A review on poly lactic acid (PLA) as a biodegradable polymer. Polymer Bulletin, 80(2), 1179–1213. https://doi.org/10.1007/s00289-022-04160-y

Thundathil, M., Nazmi, A. R., Shahri, B., Emerson, N., Müssig, J., & Huber, T. (2023). Visual–tactile perception of biobased composites. Materials, 16(5), 1844. https://doi.org/10.3390/ma16051844

Xiao, N., Felhofer, M., Antreich, S. J., Huss, J. C., Mayer, K., Singh, A., Bock, P., & Gierlinger, N. (2021). Twist and lock: Nutshell structures for high strength and energy absorption. Royal Society Open Science, 8(8), 210399. https://doi.org/10.1098/rsos.210399

Yu, Z., Wu, Y., Mou, Q., Li, X., Li, T., Cai, Z., He, L., & Li, X. (2025). Green and sustainable metal-reinforced bamboo composites with high self-bonding performances. Industrial Crops and Products, 223, 120053. https://doi.org/10.1016/j.indcrop.2024.120053

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Published

2026-02-17

How to Cite

Gutiérrez-Aldana, N., Arzate-Vázquez, I., Méndez-Méndez , J. V., Martínez-Gutiérrez, H., & Chanona-Pérez, J. J. (2026). Valorization of pistachio shells as green composite material: an approach that contributes to sustainable development. Renewable Energy, Biomass & Sustainability, 8(1), 46–53. https://doi.org/10.56845/rebs.v8i1.672

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