Uso de los polímeros metal-orgánicos en el proceso de transesterificación para la obtención de biodiésel

Raul Colorado-Peralta; José María Rivera; Elizabeth Márquez-López; Luis Pablo Amador-Gómez

doi:10.56845/terys.v3i1.226

Autores/as

Raul Colorado-Peralta Universidad Veracruzana https://orcid.org/0000-0001-9458-1800
José María Rivera Universidad Veracruzana https://orcid.org/0000-0001-9527-0131
Elizabeth Márquez-López Universidad Veracruzana https://orcid.org/0000-0002-4605-6013
Luis Pablo Amador-Gómez Universidad Veracruzana

DOI:

https://doi.org/10.56845/terys.v3i1.226

Palabras clave:

MOFs, química de coordinación, biodiésel, transesterificación, catálisis

Resumen

El uso de los polímeros metal orgánicos (MOFs, por sus siglas en inglés) como catalizadores heterogéneos en el proceso de transesterificación de aceites vegetales y otras materias primas para la producción de biodiésel, han sido de gran ayuda para la reducción de gases tóxicos, gases de efecto invernadero y otros contaminantes químicos. Se conoce que el biodiésel es un combustible amigable que ayuda a reducir los efectos producidos durante la quema de combustibles fósiles y su obtención es fácil comparada con la de los combustibles convencionales. La ventaja del uso de los MOFs en reacciones catalíticas es que pueden reutilizarse en diversas ocasiones, lo que permite obtener productos más puros y reducir la contaminación.

Citas

Agarwal, A. K. (2007). Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines. Progress in Energy and Combustion Science, 33(3), 233-271, https://doi.org/10.1016/j.pecs.2006.08.003. DOI: https://doi.org/10.1016/j.pecs.2006.08.003

Allendorf, M. D., Bauer, C. A., Bhakta, R. K. & Houk, R. J. T. (2009). Luminescent metal-organic frameworks. Chemical Society Reviews, 38(5), 1330-1352, https://doi.org/10.1039/b802352m. DOI: https://doi.org/10.1039/b802352m

Bajaj, A., Lohan, P., Jha, P. N. & Mehrotra, R. (2010). Biodiesel production through lipase catalyzed transesterification: An overview. Journal of Molecular Catalysis B: Enzymatic, 62(1), 9-14. https://doi.org/10.1016/j.molcatb.2009.09.018 DOI: https://doi.org/10.1016/j.molcatb.2009.09.018

Chozhavendhan, S., Vijay Pradhap Singh, M., Fransila, B., Praveen Kumar, R. & Karthiga Devi, G. (2020). A review on influencing parameters of biodiesel production and purification processes. Current Research in Green and Sustainable Chemistry, 1-2, 1-6, https://doi.org/10.1016/j.crgsc.2020.04.002. DOI: https://doi.org/10.1016/j.crgsc.2020.04.002

Garg, R., Sabouni, R. & Ahmadipour, M. (2023). From waste to fuel: Challenging aspects in sustainable biodiesel production from lignocellulosic biomass feedstocks and role of metal organic framework as innovative heterogeneous catalysts. Industrial Crops & Products, 206, 117554, https://doi.org/10.1016/j.indcrop.2023.117554. DOI: https://doi.org/10.1016/j.indcrop.2023.117554

Ho, W. W. S., Ng, H. K. & Gan, S. (2016). Advances in ultrasound-assisted transesterification for biodiesel production. Applied Thermal Engineering, 100, 553-563, https://doi.org/10.1016/j.applthermaleng.2016.02.058. DOI: https://doi.org/10.1016/j.applthermaleng.2016.02.058

Jafari, A., Ghorbani-Choghamarani, A. & Aghavandi, H. (2024). Simple Synthesis of Novel Cr-EDTA-MOF: A Green, Reusable, and Versatile Catalyst for the Production of Biodiesel Fuel from Oleic Acid and Palmitic Acid. ACS Omega, 9(5), 5255-5264, https://doi.org/10.1021/acsomega.3c05294. DOI: https://doi.org/10.1021/acsomega.3c05294

Javed, F., Zimmerman, W. B., Fazal, T., Hafeez, A., Mustafa, M., Rashid, N. & Rehman, F. (2023). Green synthesis of biodiesel from microalgae cultivated in industrial wastewater via microbubble induced esterification using bio-MOF-based heterogeneous catalyst. Chemical Engineering Research and Design, 189, 707-720, https://doi.org/10.1016/j.cherd.2022.12.004. DOI: https://doi.org/10.1016/j.cherd.2022.12.004

Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P. & Hupp, J. T. (2012). Metal-Organic Framework Materials as Chemical Sensors. Chemical Reviews, 112(2), 1105-1125, https://doi.org/10.1021/cr200324t. DOI: https://doi.org/10.1021/cr200324t

Lam, M. K., Lee, K. T. & Mohamed, A. R. (2010). Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances, 28(4), 500-518, https://doi.org/10.1016/j.biotechadv.2010.03.002. DOI: https://doi.org/10.1016/j.biotechadv.2010.03.002

Lee, A. F., Bennett, J. A., Manayil, J. C. & Wilson, K. (2014). Heterogeneous catalysis for sustainable biodiesel production via esterification and transesterification. Chemical Society Reviews, 43(22), 7887–7916, https://doi.org/10.1039/c4cs00189c. DOI: https://doi.org/10.1039/C4CS00189C

Leung, D. Y. C., Wu, X. & Leung, M. K. H. (2010). A review on biodiesel production using catalyzed transesterification. Applied Energy, 87(4), 1083-1095, https://doi.org/10.1016/j.apenergy.2009.10.006. DOI: https://doi.org/10.1016/j.apenergy.2009.10.006

Liu, Y. & Tang, Z. (2013). Multifunctional Nanoparticle@MOF Core-Shell Nanostructures. Advanced Materials, 25(40), 5819-5825. https://doi.org/10.1002/adma.201302781. DOI: https://doi.org/10.1002/adma.201302781

Lotero, E., Liu, Y., Lopez, D. E., Suwannakarn, K., Bruce, D. A., & Goodwin, J. G. (2005). Synthesis of biodiesel via acid catalysis. Industrial and Engineering Chemistry Research, 44(14), 5353-5363, https://doi.org/10.1021/ie049157g. DOI: https://doi.org/10.1021/ie049157g

Ma, F. & Hanna, M. A. (1999). Biodiesel production: a review. Bioresource Technology, 70(1), 1-15, https://doi.org/10.1016/S0960-8524(99)00025-5. DOI: https://doi.org/10.1016/S0960-8524(99)00025-5

Peña-Rodríguez, R., Márquez-López, E., Guerrero, A., Chiñas, L. E., Hernández-González, D. F., & Rivera, J. M. (2018). Hydrothermal synthesis of cobalt (II) 3D metal-organic framework acid catalyst applied in the transesterification process of vegetable oil. Materials Letters, 217, 117-119, https://doi.org/10.1016/j.matlet.2018.01.052. DOI: https://doi.org/10.1016/j.matlet.2018.01.052

Schuchardt, U., Sercheli, R. & Vargas, R. M. (1998). Transesterification of Vegetable Oils: a Review. Journal of the Brazilian Chemical Society, 9(1), 199-210, https://doi.org/10.1590/S0103-50531998000300002. DOI: https://doi.org/10.1590/S0103-50531998000300002

Shah, S., Sharma, S. & Gupta, M. N. (2003). Enzymatic transesterification for biodiesel production. Indian Journal of Biochemistry & Biophysics, 40(6), 392-399, http://nopr.niscpr.res.in/handle/123456789/3816.

Veljković, V. B., Avramović, J. M. & Stamenković, O. S. (2012). Biodiesel production by ultrasound-assisted transesterification: State of the art and the perspectives. Renewable and Sustainable Energy Reviews, 16(2), 1193-1209, https://doi.org/10.1016/j.rser.2011.11.022. DOI: https://doi.org/10.1016/j.rser.2011.11.022

Wang, Q. & Astruc, D. (2020). State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis. Chemical Reviews, 120(2), 1438-1511, https://doi.org/10.1021/acs.chemrev.9b00223. DOI: https://doi.org/10.1021/acs.chemrev.9b00223

Xie, W. & Wang, H. (2021). Grafting copolymerization of dual acidic ionic liquid on core-shell structured magnetic silica: A magnetically recyclable Brönsted acid catalyst for biodiesel production by one-pot transformation of low-quality oils. Fuel 283, 118893, https://doi.org/10.1016/j.fuel.2020.118893. DOI: https://doi.org/10.1016/j.fuel.2020.118893

Yadav, D., Datta, S., Saha, S., Pradhan, S., Kumari, S., Gupta, P. K., Chauhan, V., Saw, S. K. & Sahu, G. (2022). Heterogeneous Nanocatalyst for Biodiesel Synthesis. ChemistrySelect 7(28), e202201671, https://doi.org/10.1002/slct.202201671. DOI: https://doi.org/10.1002/slct.202201671

Yu, J., Mu, C., Yan, B., Qin, X., Shen, C., Xue, H. & Pang, H. (2017). Nanoparticle/MOF composites: Preparations and applications. Materials Horizons, 4(4), 557-569, https://doi.org/10.1039/c6mh00586a. DOI: https://doi.org/10.1039/C6MH00586A

Uso de los polímeros metal-orgánicos en el proceso de transesterificación para la obtención de biodiésel

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